AnswersChemistry A.1 - F26 - Jacob MetskerLab: Calorimetry and Specific Heat

Thermochemical Equations Answers

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The enthalpy of formation for C6 H6 (I) is 49.0 kJ/mol. Consider the following reaction.Is the reaction endothermic or exothermic, and what is the enthalpy of reaction? Use .

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A
exothermic; Hrxn = 49.0 kJ
Option A
B
exothermic; Hrxn = –49.0 kJ
Option B
C
endothermic; Hrxn = 49.0 kJ
Option C
D
endothermic; Hrxn = –49.0 kJ
Option D
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Hydrogen ( H2 ) reacts with bromine ( Br2 ) to produce hydrogen bromide (HBr) gas as shown in the equation below.Standard Enthalpies of FormationSubstanceDHf (kJ/mol)Br2 (l)0.0Br2 (g)30.907HBr (g)–36.4HCl (g)–92.307HI (g)26.48H2 (g)0.0I2 (g)62.438Based on the equation and the information in the table, what is the enthalpy of the reaction?

Question illustration
A
–134.6 kJ
B
–103.7 kJ
C
103.7 kJ
D
134.6 kJ
3

How is enthalpy used to predict whether a reaction is endothermic or exothermic?

A
When the enthalpy of the reactants is higher than the enthalpy of the products, the reaction is endothermic.
B
When the enthalpy of the products is higher than the enthalpy of the reactants, the reaction is exothermic.
C
When the enthalpy change of the reaction is positive, the reaction is exothermic.
D
When the enthalpy change of the reaction is positive, the reaction is endothermic.
4

Which statement about Hf is true?

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A
It is positive when the bonds of the product store more energy than those of the reactants.
B
It is zero for any pure substance in its standard state.
C
It is negative when a compound forms from elements in their standard states.
D
It is zero for any compound that is in the liquid state.
5

Ammonia (NH3 (g), Hf = –45.9 kJ/mol ) reacts with oxygen to produce nitrogen and water (H2 O(g), Hf = –241.8 kJ/mol) according to the equation below.What is the enthalpy of the reaction? Use .

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A
–3,572.1 kJ
B
–1,267.2 kJ
C
1,267.2 kJ
D
3,572.1 kJ
6

Consider the reaction.Standard Enthalpies of FormationSubstanceDHf (kJ/mol)C2 H2 (g)226.73CaCO3 (s)–1206.92CaO (s)–635.09CO (g)–110.525CO2 (g)–393.509H 2 O (I)–285.8H 2 O (g)–241.818C (s), diamond1.895C (s), graphite0.0Based on the equation and the information in the table, what is the enthalpy of the reaction? Use .

Question illustration
A
–453.46 kJ
B
–226.73 kJ
C
226.73 kJ
D
453.46 kJ
7

The enthalpies of formation of the compounds in the combustion of methane, ,are CH4 (g): Hf = –74.6 kJ/mol; CO2 (g): Hf = –393.5 kJ/mol; and H2 O(g): Hf = –241.82 kJ/mol.How much heat is released by the combustion of 2 mol of methane? Use .

Question illustration
A
80.3 kJ
Option A
B
802.5 kJ
Option B
C
1,605.1 kJ
Option C
D
6,420.3 kJ
Option D
8

Sulfur reacts with oxygen to form sulfur dioxide (SO2(g), Hf = –296.8 kJ/mol) according to the equation below.What is the enthalpy change for the reaction? Use .

Question illustration
A
–593.6 kJ
B
–296.8 kJ
C
296.8 kJ
D
593.6 kJ
9

Manganese dioxide (MnO2(s), Hf = –520.0 kJ) reacts with aluminum to form aluminum oxide (AI2O3(s), Hf = –1699.8 kJ/mol) and manganese according to the equation below.What is the enthalpy of the reaction? Use .

Question illustration
A
–1,839.6 kJ
B
–1,179.8 kJ
C
1,179.8 kJ
D
1,839.6 kJ
10

Which statement is true for most chemical reactions?

A
An energy change occurs during the breaking and forming of bonds.
B
The internal energy of the system increases during a reaction.
C
Energy is released during the formation of reactants.
D
The enthalpy of the products is higher than the enthalpy of the reactants.

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